3D Bioplotter Research Papers

Displaying all papers about Graphene Oxide (7 results)

3D Printed Polyimide Nanocomposite Aerogels for Electromagnetic Interference Shielding and Thermal Management

Advanced Materials Technologies 2023 Volume 8, Issue 14, Article 2202155

Aerogels were listed among the top ten emerging technologies in chemistry by IUPAC in 2022. Their record-breaking properties sparked the emergence of a thriving insulation market, but solutions are sought to promote additional applications. A 3D assembly process based on direct ink writing of “aerogel-in-aerogel” nanocomposites is presented. The printed polyimide-silica aerogels are non-brittle (E = 6.7 MPa) with a super-insulating thermal conductivity (20.3 mW m−1 K−1) and high thermal stability (T5wt% 447 °C). In addition, they display excellent low-loss dielectric properties and microwave transmission over all relevant communication bands and can be functionalized for electromagnetic interference (EMI) shielding. The high shape-fidelity printing, combined…

Three-dimensional-printed calcium alginate/graphene oxide porous adsorbent with super-high lead ion adsorption ability in aqueous solution

Separation and Purification Technology 2023 Volume 326, Article 124757

Using three-dimensional (3D) printing technology, a 3D calcium alginate/graphene oxide (3D CA/GO) adsorbent, with a hierarchical macroporous structure, was successfully constructed. Owing to the optimized construction process, the 3D CA/GO showed an enhanced adsorption capacity (490.2 mg/g at pH = 3.0) for lead (Pb(II)) in aqueous solution, which was two times higher than reported in the literature). Meanwhile, the selective adsorption ratio of 3D CA/GO for Pb(II) reached 99.8% when positive ions occurred. In addition, after eight adsorption–desorption cycles, the adsorption capacity did not experience a significant decrease and the structure remained stable. Meanwhile, the adsorbed Pb(II) could be eluted…

Turbulence-induced formation of emulsion gels

Ultrasonics Sonochemistry 2021 Volume 81, Article 105847

Emulsion gels have a wide range of applications. We report on a facile and versatile method to produce stable emulsion gels with tunable rheological properties. Gel formation is triggered by subjecting a mixture containing aqueous colloidal particle (CP) suspensions and water-immiscible liquids to intense turbulence, generated by low frequency (20 kHz) ultrasound or high-pressure homogenization. Through systematic investigations, requisite gel formation criteria are established with respect to both formulation and processing, including ratio/type of liquid pairs, CP properties, and turbulence conditions. Based on the emulsion microstructure and rheological properties, inter-droplet bridging and CP void-filling are proposed as universal stabilization mechanisms.…

Fabrication and characterization of mechanically competent 3D printed polycaprolactone-reduced graphene oxide scaffolds

Scientific Reports 2020 Volume 10, Article number 22210

The ability to produce constructs with a high control over the bulk geometry and internal architecture has situated 3D printing as an attractive fabrication technique for scaffolds. Various designs and inks are actively investigated to prepare scaffolds for different tissues. In this work, we prepared 3D printed composite scaffolds comprising polycaprolactone (PCL) and various amounts of reduced graphene oxide (rGO) at 0.5, 1, and 3 wt.%. We employed a two-step fabrication process to ensure an even mixture and distribution of the rGO sheets within the PCL matrix. The inks were prepared by creating composite PCL-rGO films through solvent evaporation casting…

Chondroinductive Alginate-Based Hydrogels Having Graphene Oxide for 3D Printed Scaffold Fabrication

ACS Applied Materials & Interfaces 2020 Volume 12, Issue 4, Pages 4343-4357

Scaffolds based on bioconjugated hydrogels are attractive for tissue engineering because they can partly mimic human tissue characteristics. For example, they can further increase their bioactivity with cells. However, most of the hydrogels present problems related to their processability, consequently limiting their use in 3D printing to produce tailor-made scaffolds. The goal of this work is to develop bioconjugated hydrogel nanocomposite inks for 3D printed scaffold fabrication through a micro-extrusion process having improved both biocompatibility and processability. The hydrogel is based on a photocrosslinkable alginate bioconjugated with both gelatin and chondroitin sulfate in order to mimic the cartilage extracellular matrix,…

3D printing of free-standing and flexible nitrogen doped graphene/ polyaniline electrode for electrochemical energy storage

Chemical Physics Letters 2019 Volume 728, August 2019, Pages 6-13

Flexible graphene film can be quickly realized by three-dimensional printing (3D printing), which has the potential in functional electronic devices. With a trace of cobalt ions as crosslinker, the graphene oxide sol can be converted into 3D printed ink, overcoming the disadvantage of insufficient viscosity of pure graphene oxide ink. The various graphene architectures were successfully obtained by 3D printing, moreover, graphene/polyaniline composites were obtained by electropolymerization. The specific capacitance of graphene/polyaniline electrode achieved up to 238 F/g at the current density of 0.5 A/g, which was much higher than that of graphene electrode (35 F/g).

Graphene oxide dispersions: tuning rheology to enable fabrication

Materials Horizons 2014 Volume 1, Issue 3, Pages 326-331

Here, we show that graphene oxide (GO) dispersions exhibit unique viscoelastic properties, making them a new class of soft materials. The fundamental insights accrued here provide the basis for the development of fabrication protocols for these two-dimensional soft materials, in a diverse array of processing techniques.