3D Bioplotter Research Papers

Displaying all papers by A. Gallastegui (2 results)

Mixed Ionic and Electronic Conducting Eutectogels for 3D-Printable Wearable Sensors and Bioelectrodes

Advanced Materials Technologies 2022 Volume 7, Issue 10, Article 2101680

Eutectogels are a new class of soft ion conductive materials that are attracting attention as an alternative to conventional hydrogels and costly ionic liquid gels to build wearable sensors and bioelectrodes. Herein, the first example of mixed ionic and electronic conductive eutectogels showing high adhesion, flexibility, nonvolatility, and reversible low-temperature gel transition for 3D printing manufacturing is reporting. The eutectogels consist of choline chloride/glycerol deep eutectic solvent, poly(3,4-ethylenedioxythiophene): lignin sulfonate, and gelatin as the biocompatible polymer matrix. These soft materials are flexible and stretchable, show high ionic and electronic conductivities of 7.3 and 8.7 mS cm−1, respectively, and have high…

Printable Single-Ion Polymer Nanoparticle Electrolytes for Lithium Batteries

Small Science 2024 Volume 4, Issue 3, Article 2300235

New material solutions are searched for the manufacturing and safety of current batteries. Herein, an extrusion printable polymer separator for lithium batteries based on single-ion polymer electrolytes is presented. The polymer electrolytes are based on methacrylic polymeric nanoparticles (NPs) functionalized with a lithium sulfonamide group combined with different organic plasticizers such as sulfolane and carbonates. The synthesis of the polymer NPs is carried out by emulsion copolymerization of methyl methacrylate and lithium sulfonamide methacrylate in the presence of a crosslinker, resulting in particle sizes of less than 30 nm, as shown by electron microscopy. Then polymer electrolytes are prepared by mixing…