3D Bioplotter Research Papers
Towards sustainable, direct printed, organic transistors with biocompatible copolymer gate dielectrics
We have investigated the potential of three dielectric materials to meet the future demands of green dielectrics: Polycaprolactone (PCL) thermoplastic, polyvinyl alcohol (PVA)-carrageenan (CAR) crosslinked biopolymer, and boron nitride nanotubes (BNNTs) as a nano additive in PVA. Metal–insulator–metal (MIM) capacitors and organic thin film transistors (OTFT) were built with bilayer dielectric stacks of PVA-CAR, PVA-PCL, and PVA-BNNT materials to examine their electrical properties. The PVA-CAR layer uses a cyclic freeze thaw process to crosslink PVA and CAR for superior mechanical and electrical properties to either material alone. The PVA-CAR MIM capacitors showed a dielectric constant of 23, which was found…
Direct Printed Flexible Organic Thin-Film Transistors With Cross-Linked PVA-Carrageenan Gate Dielectric
There is an urgent need to develop and implement green materials in electronic systems to minimize the negative environmental impact of traditional electronic materials. In this letter, low-temperature cross-linked polyvinyl alcohol (PVA)-carrageenan (CAR) layer is presented as a green electronic gate dielectric for high-performance organic thin-film transistors (OTFT). A metal-free, flexible OTFT, direct printed on polyaniline films using poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) gel-based gate–source–drain layers, PVA-CAR gate dielectric, and 6,13-bis(triisopropylsilylethynyl)pentacene semiconductor, is tested and characterized compared with a more conventional organic gate dielectric polymethylmethacrylate. PVA-CAR metal–dielectric–metal capacitors showed excellent dielectric properties with an average absolute dielectric constant value of 22.36 and an absolute…